Integrated Rate Equations of Chemical Reaction

IMPORTANT

Integrated Rate Equations of Chemical Reaction: Overview

This topic covers concepts, such as, Integrated Rate Equation for Zero Order Reactions, Half Life Period for Zero Order Reactions, Half-life Vs (1/a) Graph for Second Order Reaction & Integrated Rate Expression of nth Order Reactions etc.

Important Questions on Integrated Rate Equations of Chemical Reaction

HARD
IMPORTANT

A first order reaction is 20% complete in 5 minute. Calculate the time taken for the reaction to be 60% complete:

log 2.5=0.3979, log 1.25=0.0969

MEDIUM
IMPORTANT

In a first-order reaction, the concentration of reactant decreases from  800  mol/dm  3  to 50  mol/dm  3  in 2 × 102 s. The rate constant of reaction in s-1 is

MEDIUM
IMPORTANT

In a first order reaction the concentration of reactant decreases from 800 mol/dm3 to  50 mol/dm3 in 200 sec. The rate constant of reaction in s1 is

MEDIUM
IMPORTANT

The rate-constant of a reaction is 3.5×10-12s-1. The half-life of this reaction (in s) is

MEDIUM
IMPORTANT

Graph of half life of first-order reaction and initial concentration of reactant is a:

MEDIUM
IMPORTANT

Graph of half life of zero-order reaction and initial concentration of reactant is a:

HARD
IMPORTANT

The consecutive reaction XYZ takes place in a closed container. Initially, the container has A0 moles of X (and no Y and Z). The plot of total moles of the constituents in the container as a function of time will be

MEDIUM
IMPORTANT

Which among the following represents the expression for (3/4)th life of 1st  order reaction?

EASY
IMPORTANT

If the rate constant of a first order reaction is 4.606×10-3 s-1, then find the time required for 400 g of the reactant to reduce to 50 g.

EASY
IMPORTANT

If the decomposition reaction A(g)B(g) follows first order kinetics, then the graph of rate of formation of B, denoted by R, against time 't' will be

MEDIUM
IMPORTANT

If the rate constant for a first order reaction is k, then find the time required for completion of 80% of the reaction.

MEDIUM
IMPORTANT

Reactant R gives n different products Pr:r=1,2,3,,n in n parallel first order reactions. Rate constant for the formation of any produet Pr is rk where r=1,2,3,,n. For the decay of R, what is the overall rate constant in terms of k?

EASY
IMPORTANT

The rate constant for the first-order reaction is 60 s-1. How much time will it take to reduce the concentration of the reactant to 1/16 of initial value?

EASY
IMPORTANT

Which of the following curve represent zero order reaction of A  products?

EASY
IMPORTANT

The inactivation of a viral preparation in a chemical bath is found to be a first order reaction. Calculate the rate constant for the viral inactivation if in the beginning 1.5 % of the virus is inactivated per minute.

  ( Given:ln 100 98.5 =0.01511 )

HARD
IMPORTANT

Two first-order reactions have half times in the ratio of 8 : 1. The ratio of time intervals t1:t2 is:

Here, the time t1 and t2 are time period for 14th and 34th completion.

MEDIUM
IMPORTANT

Which of the following equations represent integrated rate equation of zero order reaction?

EASY
IMPORTANT

For a zero-order reaction, with the initial reactant concentration a, the time for completion of the reaction is:

HARD
IMPORTANT

The reaction AC+D was found to be second order in A. The rate constant for the reaction was determined to be 2.42 L/mol/s. If the initial concentration is 0.5 mole/L, what is the value of t12in sec?

(Express your answer by multiplying with 100 and rounding off to two significant figures)

HARD
IMPORTANT

A drop (0.05 mL) of a solution contains 3.0×10-6 moles of H+ Ions. If the rate constant of disappearance of H+ ion is 1.0×107mol litre-1 sec-1,  the time taken for  H+ ions in the drop to disappear is p×10-q. Calculate the value of q-p.

Give the nearest integer as the answer.